Lithium–sulfur batteries are a promising energy-storage technology due to their relatively low cost and high theoretical energy density. However, one of their major technical problems is the shuttling of soluble polysulfides between electrodes, resulting in rapid capacity fading. Here, we present a metal–organic framework (MOF)-based battery separator to mitigate the shuttling problem. We show that the MOF-based separator acts as an ionic sieve in lithium–sulfur batteries, which selectively sieves Li+ ions while e ciently suppressing undesired polysulfides migrating to the anode side. When a sulfur-containing mesoporous carbon material (approximately 70 wt% sulfur content) is used as a cathode composite without elaborate synthesis or surface modification, a lithium–sulfur battery with a MOF-based separator exhibits a low capacity decay rate (0.019% per cycle over 1,500 cycles). Moreover, there is almost no capacity fading after the initial 100 cycles. Our approach demonstrates the potential for MOF-based materials as separators for energy-storage applications.
上传时间: 2017-11-23
上传用户:653357637
Lithium–sulfur (Li–S) batteries with high energy density and long cycle life are considered to be one of the most promising next-generation energy-storage systems beyond routine lithium-ion batteries. Various approaches have been proposed to break down technical barriers in Li–S battery systems. The use of nanostructured metal oxides and sulfides for high sulfur utilization and long life span of Li–S batteries is reviewed here. The relationships between the intrinsic properties of metal oxide/sulfide hosts and electrochemical performances of Li–S batteries are discussed. Nanostructured metal oxides/ sulfides hosts used in solid sulfur cathodes, separators/interlayers, lithium- metal-anode protection, and lithium polysulfides batteries are discussed respectively. Prospects for the future developments of Li–S batteries with nanostructured metal oxides/sulfides are also discussed.
上传时间: 2017-11-23
上传用户:653357637
In this paper we present a classifier called bi-density twin support vector machines (BDTWSVMs) for data classification. In the training stage, BDTWSVMs first compute the relative density degrees for all training points using the intra-class graph whose weights are determined by a local scaling heuristic strategy, then optimize a pair of nonparallel hyperplanes through two smaller sized support vector machine (SVM)-typed problems. In the prediction stage, BDTWSVMs assign to the class label depending on the kernel density degree-based distances from each test point to the two hyperplanes. BDTWSVMs not only inherit good properties from twin support vector machines (TWSVMs) but also give good description for data points. The experimental results on toy as well as publicly available datasets indicate that BDTWSVMs compare favorably with classical SVMs and TWSVMs in terms of generalization
标签: recognition Bi-density machines support pattern vector twin for
上传时间: 2019-06-09
上传用户:lyaiqing
With billions of ‘people and things’ becoming increasingly connected, the need to combine the potential of unlicensed and licensed wireless services has become an imperative for the operators, cities, high density venues and players focused on key market opportunities such as IoT, big data and 5G. The WBA has developed Vision 2020 to harness its experience of creating seamlessly interconnected wireless services in new and emerging areas.
上传时间: 2020-05-26
上传用户:shancjb
This book is intended to help electric power and telephone company personnel and individuals interested in properly protecting critical tele communications circuits and equipment located in high voltage (HV) environments and to improve service reliability while maintaining safe working conditions. Critical telecommunications circuits are often located in HV environments such as electric utility power plants, substations, cell sites on power towers, and standalone telecommuni cations facilities such as 911 call centers and mountaintop telecom munications sites.
标签: Protection Voltage High
上传时间: 2020-05-27
上传用户:shancjb
OSCILLATORS are key building blocks in integrated transceivers. In wired and wireless communication terminals, the receiver front-end selects, amplifies and converts the desired high-frequency signal to baseband. At baseband the signal can then be converted into the digital domain for further data processing and demodula- tion. The transmitter front-end converts an analog baseband signal to a suitable high- frequency signal that can be transmitted over the wired or wireless channel.
标签: High-Frequency Oscillator Design
上传时间: 2020-05-27
上传用户:shancjb
The goal of this book is to introduce the simulation methods necessary to describe the behaviour of semiconductor devices during an electrostatic discharge (ESD). The challenge of this task is the correct description of semiconductor devices under very high current density and high temperature transients. As it stands, the book can be no more than a snapshot and a summary of the research in this field during the past few years. The authors hope that the book will provide the basis for further development of simulation methods at this current frontier of device physics.
标签: Development Protection ESD
上传时间: 2020-06-05
上传用户:shancjb
The first edition as well as its forerunner of Kuffel and Abdullah published in 1970 and their translations into Japanese and Chinese languages have enjoyed wide international acceptance as basic textbooks in teaching senior under- graduate and postgraduate courses in High-Voltage Engineering. Both texts have also been extensively used by practising engineers engaged in the design and operation of high-voltage equipment. Over the years the authors have received numerous comments from the text’s users with helpful suggestions for improvements. These have been incorporated in the present edition. Major revisions and expansion of several chapters have been made to update the continued progress and developments in high-voltage engineering over the past two decades.
标签: Engineering Voltage High
上传时间: 2020-06-07
上传用户:shancjb
The PW2301A uses advanced trench It utilizes the latest processing techniques to achieve the highcell density and reduces the on-resistance with high repetitive avalanche rating. These featurescombine to make this design an extremely efficient and reliable device for use in power switchingapplication and a wide variety of other applications
标签: pw2301a
上传时间: 2022-02-11
上传用户:
The PW8205A8TS is the highest performance trench N-ch MOSFETs with extreme high cell density,which provide excellent RDSON and gate charge for most of the small power switching and loadswitch applications. The meet the RoHS and Product requirement with full function reliabilityapproved .
标签: 8205a8
上传时间: 2022-02-14
上传用户:wangshoupeng199